I've seen this photo before. Before the drawing. [Personal work, 2013 -Cameron Stewart spectacular illustrator, wonderful mix of black and white control and crosshatching shading, especially with hair and background]
I honestly don't know who they are. The girl's attitude stance, her school uniform and her look's, look's like Misaki from Kaichou wa Maid-sama! But the guy isn't her hot Usui. I would love to find out what anime this is.